May 30, 2024

Solubility of gas in liquids

Solubility of gas in liquids

The solubility of gases in liquids is an important phenomenon that is influenced by several factors such as temperature, pressure, and the nature of the gas and solvent. The solubility of gases in liquids is typically measured in terms of the gas concentration in the liquid phase, often expressed in units of molarity or mole fraction.

The solubility of gases in liquids can be described by Henry’s Law, which states that at a constant temperature, the amount of gas that dissolves in a liquid is directly proportional to the partial pressure of the gas above the liquid. The equation for Henry’s Law is given as:

C = kH * P

where C is the concentration of the gas in the liquid phase, P is the partial pressure of the gas above the liquid, and kH is the Henry’s Law constant, which is a measure of the solubility of the gas in the liquid.

The solubility of gases in liquids is influenced by temperature, with an increase in temperature leading to a decrease in the solubility of gases in liquids. This is because an increase in temperature leads to an increase in the kinetic energy of the gas molecules, causing them to escape from the liquid phase and reducing the amount of gas that can dissolve.

The solubility of gases in liquids is also influenced by pressure. An increase in pressure above the liquid leads to an increase in the solubility of gases in liquids, while a decrease in pressure leads to a decrease in the solubility of gases in liquids. This is because an increase in pressure causes more gas molecules to come into contact with the liquid, increasing the chances of them dissolving in the liquid phase.

The nature of the gas and solvent can also influence the solubility of gases in liquids. For example, gases that are more polar or have higher molecular weight tend to be less soluble in nonpolar solvents. Similarly, gases that are less polar or have lower molecular weight tend to be more soluble in polar solvents.

In summary, the solubility of gases in liquids is an important phenomenon that is influenced by several factors, such as temperature, pressure, and the nature of the gas and solvent. Henry’s Law is commonly used to describe the solubility of gases in liquids, and understanding the factors that influence solubility is crucial for designing gas delivery systems and understanding various biological processes such as gas exchange in the lungs.

Second Year B Pharm Notes, Syllabus, Books, PDF Subjectwise/Topicwise

S Y B Pharm Sem IIIS Y B Pharm Sem IV
BP301T Pharmaceutical Organic Chemistry II TheoryBP401T Pharmaceutical Organic Chemistry III Theory
BP302T Physical Pharmaceutics I TheoryBP402T Medicinal Chemistry I Theory
BP303T Pharmaceutical Microbiology TheoBP403T Physical Pharmaceutics II Theory
BP304T Pharmaceutical Engineering TheoryBP404T Pharmacology I Theory
BP305P Pharmaceutical Organic Chemistry II PracticalBP405T Pharmacognosy I Theory
BP306P Physical Pharmaceutics I PracticalBP406P Medicinal Chemistry I Practical
BP307P Pharmaceutical Microbiology PracticalBP407P Physical Pharmaceutics II Practical
BP308P Pharmaceutical Engineering PracticalBP408P Pharmacology I Practical
BP409P Pharmacognosy I Practical

Suggested readings:


SOLUBILITY OF GAS IN LIQUIDS from AMAR RAVAL